Advances in Homogeneous Photocatalytic Organic Synthesis with Colloidal Quantum Dots

Colloidal quantum dots: synthesis, properties and applications

Synthesis of colloidal Zn(Te,Se) alloy quantum dots

Colloidal Zn(Te1−xSex) quantum dots (QDs), which are highly mismatched semiconductor alloys, were synthesized by the hot injection of an organometallic solution, and the composition and size dependence of their optical gap were studied together with the theoretical calculation using the finite-depth-well effective mass approximation. The optical gaps exhibited considerable negative deviation fr...

Photoluminescence upconversion in colloidal CdTe quantum dots

Efficient photoluminescence ~PL! up-conversion has been observed in colloidal CdTe quantum dots with an energy gain of as high as 360 meV. Compared with the normal PL, the peak energy of this up-converted PL ~UCPL! shows a redshift of about 80 meV, and the corresponding radiative lifetime becomes nearly twice as long. This UCPL is attributed to the carrier recombination involving surface states...

Exciton Dynamics in InSb Colloidal Quantum Dots.

Extraordinarily fast biexciton decay times and unexpectedly large optical gaps are two striking features observed in InSb colloidal quantum dots that have remained so far unexplained. The former, should its origin be identified as an Auger recombination process, would have important implications regarding carrier multiplication efficiency, suggesting these nanostructures as potentially ideal ac...

Colloidal transition-metal-doped ZnO quantum dots.

Methods for introducing new magnetic, optical, electronic, photophysical, or photochemical properties to semiconductor nanocrystals are attracting intense applications-oriented interest. In this communication, we report the preparation and electronic absorption spectroscopy of colloidal ZnO DMS-QDs. Our synthetic procedure involves modification of literature methods known to yield highly crysta...